Browsing by Subject "Nonplanar porphyrins"
Now showing items 1-4 of 4
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Conformational Re-engineering of Porphyrins as Receptors with Switchable NH???X-Type Binding Modes
(2019)The selectivity and functional variability of porphyrin cofactors are typically based on substrate binding of metalloporphyrins wherein the pyrrole nitrogen units only serve to chelate the metal ions. Yet, using the porphyrin ... -
Investigating the Impact of Conformational Molecular Engineering on the Crystal Packing of Cavity Forming Porphyrins
(2019)Herein we report the synthesis of 5,10,15,20-tetraaryl-(X)-substituted- 2,3,7,8,12,13,17,18-octaethylporphyrins (OETArXPs) and a structural investigation of their solid-state properties via small molecule X-ray diffraction. ... -
Konformativer Umbau von Porphyrinen als Rezeptoren mit schaltbaren N‐H⋅⋅⋅X‐Bindungsmodi
(2019)Die Selektivität und funktionale Variabilität von Porphyrinkofaktoren basiert typischerweise auf der Substratbindung durch Metalloporphyrine, wobei die Pyrrolstickstoffatome nur zur Chelatisierung der Metallionen dienen. ... -
Nonplanar Porphyrins by N-Substitution: A Neglected Pathway
(2018)N‐substitution of porphyrins has been a neglected route towards nonplanar porphyrins for the past decades. Previously, they featured in a host of potential medicinal and biochemical applications. However, tailored syntheses ...