dc.contributor.author | SENGE, MATHIAS | |
dc.date.accessioned | 2013-10-22T10:13:03Z | |
dc.date.available | 2013-10-22T10:13:03Z | |
dc.date.issued | 2011 | |
dc.date.submitted | 2011 | en |
dc.identifier.citation | Plunkett, S.; Senge, M. O., Synthesis of Unsymmetrically meso-Substituted Porphyrins, ECS Transactions, 35, 2011, 147-157 | en |
dc.identifier.other | Y | |
dc.identifier.uri | http://hdl.handle.net/2262/67528 | |
dc.description | PUBLISHED | en |
dc.description.abstract | The continued development of new medicinal and industrial uses
of highly substituted porphyrins, especially in the fields of
photodynamic therapy, nonlinear optics and electron transfer
systems, has led to a resurgent interest in developing new
methodologies for porphyrin synthesis. The porphyrins in question,
so called ABCD-type porphyrins, have mixed meso substituents,
making them highly unsymmetric and thus not synthetically
available through classical condensation routes. Synthetic
strategies towards the formation of meso substituted porphyrins
have been extensively researched over the last decade with various
routes now available. While methods using mixed condensations
are still preferred for systems with high symmetry, the number of
possible products makes it an unviable route for the synthesis of
the more useful non symmetric porphyrins. To this end novel
syntheses of ABCD-type porphyrins have been developed using
synthetic manipulations of pre-formed porphyrin scaffolds with
various organolithium reagents and Pd catalysed metal couplings | en |
dc.description.sponsorship | Our recent work in this area was supported by a grant from Science Foundation
Ireland (SFI P.I. 09/IN.1/B2650). | en |
dc.format.extent | 147-157 | en |
dc.language.iso | en | en |
dc.relation.ispartofseries | ECS Transactions; | |
dc.relation.ispartofseries | 35; | |
dc.rights | Y | en |
dc.subject.other | Porphyrins | |
dc.title | Synthesis of Unsymmetrically meso-Substituted Porphyrins | en |
dc.type | Journal Article | en |
dc.type.supercollection | scholarly_publications | en |
dc.type.supercollection | refereed_publications | en |
dc.identifier.peoplefinderurl | http://people.tcd.ie/sengem | |
dc.identifier.rssinternalid | 78005 | |
dc.rights.ecaccessrights | OpenAccess | |