dc.contributor.author | SENGE, MATHIAS | en |
dc.contributor.author | MCCABE, THOMAS | en |
dc.contributor.author | RYAN, AOIFE | en |
dc.contributor.author | PLUNKETT, SHANE | en |
dc.date.accessioned | 2014-04-08T12:22:09Z | |
dc.date.available | 2014-04-08T12:22:09Z | |
dc.date.issued | 2014 | en |
dc.date.submitted | 2014 | en |
dc.identifier.citation | Ryan, A.A., Plunkett, S., Casey, A., McCabe, T., Senge, M.O., From thioether substituted porphyrins to sulfur linked porphyrin dimers: An unusual SNAr via thiolate displacement?, Chemical Communications, 50, 3, 2014, 353-355 | en |
dc.identifier.other | Y | en |
dc.identifier.uri | http://hdl.handle.net/2262/68437 | |
dc.description | PUBLISHED | en |
dc.description.abstract | Treatment of meso 2-ethylhexyl-3-mercaptopropionate substituted porphyrins with base at room temperature generated a porphyrin thiolate anion which in situ reacted in a nucleophilic aromatic substitution (SNAr) reaction with remaining thioether derivative. This reaction yielded S-linked bisporphyrins in good yields, with mechanistic insight obtained via displacement reactions. Additionally, SNAr of the thioether chain was achieved using S- and organolithium nucleophiles. | en |
dc.format.extent | 353-355 | en |
dc.language.iso | en | en |
dc.relation.ispartofseries | Chemical Communications | en |
dc.relation.ispartofseries | 50 | en |
dc.relation.ispartofseries | 3 | en |
dc.rights | Y | en |
dc.subject | Chemistry | en |
dc.title | From thioether substituted porphyrins to sulfur linked porphyrin dimers: An unusual SNAr via thiolate displacement? | en |
dc.type | Journal Article | en |
dc.type.supercollection | scholarly_publications | en |
dc.type.supercollection | refereed_publications | en |
dc.identifier.peoplefinderurl | http://people.tcd.ie/sengem | en |
dc.identifier.peoplefinderurl | http://people.tcd.ie/tmccabe | en |
dc.identifier.peoplefinderurl | http://people.tcd.ie/ryana41 | en |
dc.identifier.rssinternalid | 93492 | en |
dc.identifier.doi | http://dx.doi.org/10.1039/c3cc46828c | en |
dc.rights.ecaccessrights | OpenAccess | |