dc.contributor.author | BAKER, ROBERT | en |
dc.date.accessioned | 2014-06-03T12:52:12Z | |
dc.date.available | 2014-06-03T12:52:12Z | |
dc.date.issued | 2005 | en |
dc.date.submitted | 2005 | en |
dc.identifier.citation | R.J. Baker, C. Jones and M. Kloth, Oxidation reactions of an anionic gallium(I) N-heterocyclic carbene analogue with group 16 compounds., Dalton Trans, 2005, 2106, 2110 | en |
dc.identifier.other | Y | en |
dc.identifier.uri | http://hdl.handle.net/2262/69570 | |
dc.description | PUBLISHED | en |
dc.description.abstract | The reactivity of an anionic gallium(I) heterocycle, [K(tmeda)][:Ga([N(Ar)C(H)]2)], Ar = C6H3Pr(i)2-2,6, towards sources of elemental chalcogens and diorgano-dichalcogenides has been investigated and comparisons drawn with the reactivity of the valence isoelectronic N-heterocyclic carbene class of ligand. The reactions of the heterocycle with N2O or (Te)PEt3 yielded the dimeric, dianionic gallium(III) complexes, [K(L)]2[(mu-E)Ga([N(Ar)C(H)]2)]2, E = O, L = tmeda; E = Te, L = THF. Treatment of [K(tmeda)][:Ga([N(Ar)C(H)]2)] with the diphenyl dichalcogenides, PhEEPh, E = Se or Te, gave the one dimensional polymer, [K[(PhSe)2Ga([N(Ar)C(H)]2)]]infinity and the monomeric complex, [K(OEt2)3][(PhTe)2Ga([N(Ar)C(H)]2)], respectively. The X-ray crystal structures of the four complexes are reported. | en |
dc.format.extent | 2106 | en |
dc.format.extent | 2110 | en |
dc.language.iso | en | en |
dc.relation.ispartofseries | Dalton Trans | en |
dc.rights | Y | en |
dc.subject | Chemistry | en |
dc.title | Oxidation reactions of an anionic gallium(I) N-heterocyclic carbene analogue with group 16 compounds. | en |
dc.type | Journal Article | en |
dc.type.supercollection | scholarly_publications | en |
dc.type.supercollection | refereed_publications | en |
dc.identifier.peoplefinderurl | http://people.tcd.ie/bakerrj | en |
dc.identifier.rssinternalid | 57427 | en |
dc.identifier.doi | http://dx.doi.org/10.1039/b505085e | en |
dc.rights.ecaccessrights | openAccess | |