| dc.contributor.author | BAKER, ROBERT | en |
| dc.date.accessioned | 2014-06-03T12:55:25Z | |
| dc.date.available | 2014-06-03T12:55:25Z | |
| dc.date.issued | 2005 | en |
| dc.date.submitted | 2005 | en |
| dc.identifier.citation | R.J. Baker, C. Jones and D.M. Murphy,, Evidence for the first oxidative addition of a transition metal into a digallane(4): Synthesis, structural characterisation and EPR studies of [Cp2ZrIII{Ga[N(Ar)C(H)]2}2][Li(THF)4], Ar = C6H3Pri2-2,6., Chem. Commun.,, 2005, 1339, 1341 | en |
| dc.identifier.other | Y | en |
| dc.identifier.uri | http://hdl.handle.net/2262/69571 | |
| dc.description | PUBLISHED | en |
| dc.description.abstract | Treatment of “ZrCp2” with the digallane(4), [{Ga[N(Ar)C(H)]2}2], Ar = C6H3Pri2-2,6, in the presence of excess BunLi leads to the first example of a gallyl–Group 4 complex, [Cp2Zr{Ga[N(Ar)C(H)]2}2][Li(THF)4], via an unprecedented oxidative insertion reaction; the paramagnetic complex has been characterised by X-ray crystallography and EPR spectroscopy. | en |
| dc.format.extent | 1339 | en |
| dc.format.extent | 1341 | en |
| dc.language.iso | en | en |
| dc.relation.ispartofseries | Chem. Commun., | en |
| dc.rights | Y | en |
| dc.subject | Chemistry | en |
| dc.title | Evidence for the first oxidative addition of a transition metal into a digallane(4): Synthesis, structural characterisation and EPR studies of [Cp2ZrIII{Ga[N(Ar)C(H)]2}2][Li(THF)4], Ar = C6H3Pri2-2,6. | en |
| dc.type | Journal Article | en |
| dc.type.supercollection | scholarly_publications | en |
| dc.type.supercollection | refereed_publications | en |
| dc.identifier.peoplefinderurl | http://people.tcd.ie/bakerrj | en |
| dc.identifier.rssinternalid | 57424 | en |
| dc.identifier.doi | http://dx.doi.org/10.1039/b417720g | en |
| dc.rights.ecaccessrights | openAccess | |
