| dc.contributor.author | BAKER, ROBERT | en |
| dc.date.accessioned | 2015-12-09T12:45:29Z | |
| dc.date.available | 2015-12-09T12:45:29Z | |
| dc.date.issued | 2015 | en |
| dc.date.submitted | 2015 | en |
| dc.identifier.citation | Dipti Patel, Ashley J. Wooles, Emtithal Hashem, Harrison Omorodion, Robert J. Baker and Stephen T. Liddle, Comments on reactions of oxide derivatives of uranium with hexachloropropene to give UCl4, New Journal of Chemistry, 2015, 7559-7562 | en |
| dc.identifier.other | Y | en |
| dc.identifier.uri | http://hdl.handle.net/2262/75249 | |
| dc.description | PUBLISHED | en |
| dc.description | DOI: 10.1039/c5nj00476d | en |
| dc.description.abstract | We report that U3O8, UO2(NO3)2·6H2O, and UO2Cl2 react with hexachloropropene (HCP) to give UCl4 in 60, 100, and 92% yields, respectively, and report a protocol to recycle the HCP. This renders the preparation of UCl4 more accessible and sustainable. 2,5-Dichlorohexachlorofulvene has been identified as a significant by-product from these reactions | en |
| dc.description.sponsorship | The authors are grateful to the Royal Society, EPSRC, ERC,
University of Nottingham, UK National Nuclear Laboratory,
COST, and Trinity College Dublin and the Environmental
Protection Agency (EPA-2012-WRM-PhD-7) for generous and
continued support of their work. | en |
| dc.format.extent | 7559-7562 | en |
| dc.language.iso | en | en |
| dc.relation.ispartofseries | New Journal of Chemistry | en |
| dc.rights | Y | en |
| dc.title | Comments on reactions of oxide derivatives of uranium with hexachloropropene to give UCl4 | en |
| dc.type | Journal Article | en |
| dc.type.supercollection | scholarly_publications | en |
| dc.type.supercollection | refereed_publications | en |
| dc.identifier.peoplefinderurl | http://people.tcd.ie/bakerrj | en |
| dc.identifier.rssinternalid | 103171 | en |
| dc.identifier.doi | http://dx.doi.org/10.1039/c5nj00476d | en |
| dc.rights.ecaccessrights | openAccess | |
| dc.identifier.orcid_id | 0000-0003-1416-8659 | en |
