Magnetic nanoparticle-supported catalysts and novel organocatalysts for enantioselective synthesis
Citation:
Oliver Gleeson, 'Magnetic nanoparticle-supported catalysts and novel organocatalysts for enantioselective synthesis', [thesis], Trinity College (Dublin, Ireland). School of Chemistry, 2013, pp 208Download Item:
Abstract:
A study concerning the immobihsation onto magnetic nanoparticles of two useful classes of chiral organocatalyst which rely on a confluence of weak, easily perturbed van der Waals and hydrogen bonding interactions to promote enantioselective reactions has been undertaken for the first time. The catalysts were evaluated in two synthetically useful reaction classes: the kinetic resolution of sec-alcohols and the conjugate addition of dimethyl malonate to a nitroolefin.
Author: Gleeson, Oliver
Advisor:
Connon, StephenQualification name:
Doctor of Philosophy (Ph.D.)Publisher:
Trinity College (Dublin, Ireland). School of ChemistryNote:
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Full text availableKeywords:
Chemistry, Ph.D., Ph.D. Trinity College DublinMetadata
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