| dc.contributor.author | Garcia Melchor, Max | en |
| dc.date.accessioned | 2019-08-20T12:44:55Z | |
| dc.date.available | 2019-08-20T12:44:55Z | |
| dc.date.issued | 2018 | en |
| dc.date.submitted | 2018 | en |
| dc.identifier.citation | Peñas-Defrutos, M. N.; Bartolomé, C.; García-Melchor, M.; Espinet, P., Hidden aryl-exchange processes in stable 16e RhIII [RhCp*Ar2] complexes, and their unexpected transmetalation mechanism, Chemical Communications, 54, 2018, 984 - 987 | en |
| dc.identifier.other | Y | en |
| dc.identifier.uri | http://hdl.handle.net/2262/89247 | |
| dc.description | PUBLISHED | en |
| dc.description.abstract | Experiments mixing the stable 16e 5-coordinate complexes [RhCp∗Ar2] (Cp∗ = C5Me5; Ar = C6F5, C6F3Cl2-3,5) uncover fast aryl transmetalations. Unexpectedly, as supported computationally, these exchanges are not spontaneous, but catalyzed by minute amounts of 18e (μ-OH)2[RhCp∗Ar]2 as a source of 16e [RhCp∗Ar(OH)]. The OH group is an amazingly efficient bridging partner to diminish the activation barrier of transmetalation. | en |
| dc.format.extent | 984 | en |
| dc.format.extent | 987 | en |
| dc.language.iso | en | en |
| dc.relation.ispartofseries | Chemical Communications | en |
| dc.relation.ispartofseries | 54 | en |
| dc.rights | Y | en |
| dc.subject | Oxidation | en |
| dc.subject | Ruthenium | en |
| dc.subject | Electrocatalytic water | en |
| dc.title | Hidden aryl-exchange processes in stable 16e RhIII [RhCp*Ar2] complexes, and their unexpected transmetalation mechanism | en |
| dc.type | Journal Article | en |
| dc.type.supercollection | scholarly_publications | en |
| dc.type.supercollection | refereed_publications | en |
| dc.identifier.peoplefinderurl | http://people.tcd.ie/garciamm | en |
| dc.identifier.rssinternalid | 180540 | en |
| dc.identifier.doi | https://doi.org/10.1039/C7CC09352G | en |
| dc.rights.ecaccessrights | openAccess | |
| dc.identifier.rssuri | http://pubs.rsc.org/en/Content/ArticleLanding/2018/CC/C7CC09352G#!divAbstract | en |
| dc.identifier.orcid_id | 0000-0003-1348-4692 | en |
