| dc.contributor.author | Colavita, Paula | |
| dc.contributor.author | Scanlan, Eoin | |
| dc.contributor.author | Maffeis, Viviana | |
| dc.contributor.author | McCourt, Ruairí | |
| dc.contributor.author | Petracca, Rita | |
| dc.contributor.author | Laethem, Olivier | |
| dc.contributor.author | Camisasca, Adalberto | |
| dc.contributor.author | Giordani, Silvia | |
| dc.date.accessioned | 2019-10-22T11:38:23Z | |
| dc.date.available | 2019-10-22T11:38:23Z | |
| dc.date.issued | 2018 | |
| dc.date.submitted | 2018 | en |
| dc.identifier.citation | Maffeis, V., McCourt, R.O., Petracca, R., Laethem, O., Camisasca, A., Colavita, P.E., Giordani, S. & Scanlan, E.M. Photocatalytic Initiation of Radical Thiol-ene Reactions Using Carbon-Bi2O3 Nanocomposites, ACS Applied Nano Materials, 1, 2018, 4120 - 4126 | en |
| dc.identifier.other | Y | |
| dc.identifier.uri | https://pubs.acs.org/doi/10.1021/acsanm.8b00870 | |
| dc.identifier.uri | http://hdl.handle.net/2262/89854 | |
| dc.description | PUBLISHED | en |
| dc.description.abstract | A mild, inexpensive, and general photocatalytic initiation protocol for anti-Markovnikov hydrothiolation of olefins using carbon nanomaterial/metal oxide (carbon NM-MO) composites is reported. Graphene oxide (GO), nanodiamonds (ND), and carbon nano-onions (CNO) displaying bismuth or tungsten oxide nanoparticles adhered to the surface and function as highly efficient photocatalysts for thiol–ene ligation under both UV and visible-light-mediated conditions. The straightforward catalyst preparation, excellent overall yields, ease of purification, and broad substrate scope render this a highly versatile method for bioconjugation. | en |
| dc.format.extent | 4120 | en |
| dc.format.extent | 4126 | en |
| dc.language.iso | en | en |
| dc.relation.ispartofseries | ACS Applied Nano Materials; | |
| dc.relation.ispartofseries | 1; | |
| dc.relation.ispartofseries | ;8 | |
| dc.rights | Y | en |
| dc.subject | Thiol−ene | en |
| dc.subject | Radical | en |
| dc.subject | Photocatalysis | en |
| dc.subject | Graphene | en |
| dc.subject | Metal oxide | en |
| dc.subject | Nanomaterials | en |
| dc.title | Photocatalytic Initiation of Radical Thiol-ene Reactions Using Carbon-Bi2O3 Nanocomposites | en |
| dc.type | Journal Article | en |
| dc.type.supercollection | scholarly_publications | en |
| dc.type.supercollection | refereed_publications | en |
| dc.identifier.peoplefinderurl | http://people.tcd.ie/colavitp | |
| dc.identifier.peoplefinderurl | http://people.tcd.ie/scanlae | |
| dc.identifier.rssinternalid | 195664 | |
| dc.identifier.doi | https://doi.org/10.1021/acsanm.8b00870 | |
| dc.rights.ecaccessrights | openAccess | |
| dc.subject.TCDTheme | Immunology, Inflammation & Infection | en |
| dc.subject.TCDTheme | Nanoscience & Materials | en |
| dc.identifier.orcid_id | 0000-0003-1008-2874 | |
| dc.contributor.sponsor | Science Foundation Ireland (SFI) | en |
| dc.contributor.sponsorGrantNumber | 15/CDA/3310 | en |
