dc.contributor.advisor | Draper, Sylvia | |
dc.contributor.author | Nolan, Deanne | |
dc.date.accessioned | 2019-11-13T13:25:51Z | |
dc.date.available | 2019-11-13T13:25:51Z | |
dc.date.issued | 2011 | |
dc.identifier.citation | Deanne Nolan, 'Bipyridyl alkynyl-based polyphenylenes : tuning photoluminescence in metal-organic chromophores', [thesis], Trinity College (Dublin, Ireland). School of Chemistry, 2011, pp 324 | |
dc.identifier.other | THESIS 9010 | |
dc.identifier.uri | http://hdl.handle.net/2262/90454 | |
dc.description.abstract | Chapter 1 introduces two series of novel polyphenylene molecules with inherent ligand
functionality. These are prepared via a sequence of Sonogashira cross-coupling reactions
and [2+4] Diels-Alder cycloadditions and are fully characterised by NMR spectroscopy
and analytical methods. The first series are asymmetric oligophenylene-substituted
bipyridines, in which the polyaryl pendant is systematically increased in size, from a single
phenyl-acetylene to a dendritic penta-phenyl benzene. The second ligand series represents
a family of acetylene-functionalised hexaphenylbenzene molecules, from a single
acetylene substituent to ortho and para configured di-ethynyl units. The alkynyl
substituent allows an extension of π-electron delocalisation. | |
dc.format | 1 volume | |
dc.language.iso | en | |
dc.publisher | Trinity College (Dublin, Ireland). School of Chemistry | |
dc.relation.isversionof | http://stella.catalogue.tcd.ie/iii/encore/record/C__Rb14609226 | |
dc.subject | Chemistry, Ph.D. | |
dc.subject | Ph.D. Trinity College Dublin. | |
dc.title | Bipyridyl alkynyl-based polyphenylenes : tuning photoluminescence in metal-organic chromophores | |
dc.type | thesis | |
dc.type.supercollection | thesis_dissertations | |
dc.type.supercollection | refereed_publications | |
dc.type.qualificationlevel | Doctoral | |
dc.type.qualificationname | Doctor of Philosophy (Ph.D.) | |
dc.rights.ecaccessrights | openAccess | |
dc.format.extentpagination | pp 324 | |
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