Evidence for the formation of an intermediate complex in the direct metalation of tetra(4-bromophenyl)-porphyrin on the Cu(111) surface
Citation:
Doyle, CM, Krasnikov, SA, Sergeeva, NN, Preobrajenski, AB, Vinogradov, NA, Sergeeva, YN, Senge, MO, Cafolla, AA, Evidence for the formation of an intermediate complex in the direct metalation of tetra(4-bromophenyl)-porphyrin on the Cu(111) surface, CHEMICAL COMMUNICATIONS, 47, 2011, 12134 - 12136Download Item:
Abstract:
A strong molecule?surface interaction between free-base-tetra-
(4-bromophenyl)-porphyrin and Cu(111) results in a distortion of
both the molecule and the underlying copper surface in the vicinity
of the molecule. This in turn leads to the formation of an
intermediate complex due to bonding between the iminic nitrogens
and surface copper atoms.
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Author: SENGE, MATHIAS
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CHEMICAL COMMUNICATIONS;47;
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