Browsing by Subject "Nonplanar Porphyrins"
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Molecular Engineering of Porphyrins as Organocatalysts and Methods Development for New Highly Substituted Porphyrins
(Trinity College Dublin. School of Chemistry. Discipline of Chemistry, 2019)Chapter 1 introduces the N–H…X binding motif in tetrapyrroles, which forms the basis of the research carried out on organocatalytically active porphyrins in Chapters 3.1–3.3. Specifically, the role of porphyrin(oid) ligands ... -
Steric Repulsion Induced Conformational Switch in Supramolecular Structures
(2022)Inspired by the rigidified architecture of ‘picket-fence’ systems, we propose a strategy utilizing strain to impose intramolecular tension in already peripherally overcrowded structures leading to selective atropisomeric ...